Frank Ortega wrote:Has anyone done a study and comparison of the alloys in vintage mouthpieces?
I find that some of my favorite mouthpieces are from the 1920's and that they produce a warm and colorful sound.
I would be willing to bet that the difference you note has to do with shape and not material. Think of it this way: Two different brass alloys will have nearly identical stiffness, the same density, and only slightly different strength. And given that a mouthpiece is never stressed to anywhere near its strength (except when it's dropped on the concrete), the difference in strength has no effect on the mouthpiece behavior. Thus, density (as it affects mass) and stiffness will define the behavior of mouthpiece material.
The question is, how much does stiffness and mass affect that behavior? I'm thinking: Not much.
All the various alloys of brass vary by only a few percentage points in density and stiffness. Even the bronze mouthpieces are only slightly denser, but their stiffness is about the same as brass.
But plastic mouthpieces are
dramatically different. Brass is 45 times stiffer as a material than is Lexan, and over 7 times as dense. If a plastic mouthpiece has the same basic shape as a brass mouthpiece, it will weigh a seventh as much and have about 2% of its stiffness. Yet the plastic mouthpiece is not fundamentally different than a brass mouthpiece in the sound it produces. Slight different, perhaps--though even that can be argued. But not fundamentally different.
On a scale that could show the properties of both Lexan and brass, all the various brass alloys could be represented by a single dot. If the performance difference between Lexan and brass is subtle, the performance difference between different brasses is negligible.
And let's not forget that absolute mass and stiffness are controlled by the amount and placement of the material. The modulus applies to the material itself, but has to be multiplied by the cross-sectional area of the brass to determine stiffness across that plane. And mass is the product of density times volume. Mouthpiece outer shapes have varied from zero up to perhaps a factor of three to six (in the case of mouthpieces that look like the bottom half of a can of Red Bull). These differences dwarf the few percentage points of differences in brass alloy density and stiffness properties. People argue endlessly over those differences and whether they are real. If you really want to replicate an old mouthpiece, you have to replicate the outer shape as much as the inner shape. But I think even that doesn't have much effect.
Here are some numbers for different brass alloys (first number is percentage copper, second is percentage zinc):
(Density in pounds/cubic inch and modulus of elasticity in psi)
90-10 Commercial Bronze:
Density: .317
Modulus of elasticity: 16,700,000
85-15 "Red" Brass:
Density: .316
Modulus of elasticity: 16,700,000
80-20 "Low" brass:
Density: .313
Modulus of elasticity: 16,000,000
70-30 "Cartridge" Brass:
Density: .308
Modulus of elasticity: 16,000,000
65-35 "Yellow" Brass:
Density: .306
Modulus of elasticity: 15,200,000
60-40 Type 360 "Free-cutting" brass:
Density: .307
Modulus of elasticity: 14,100,000
Note that "yellow" and "red" mean different things in the materials world than they do in the tuba world.
Now, here's Lexan:
Density: .043
Modulus of elasticity: 339,000
And, because someone may be curious:
304L Stainless Steel (What G&W use, and I assume Dave Houser uses something similar):
Density: .289
Modulus of elasticity: 28,500,000
Typical titanium-aluminum-vanadium alloy (Ivan and Robert use an alloy with 6% aluminum and 4% vanadium):
Density: .160
Modulus of elasticity: 16,510,000
Rick "it's all about the shape" Denney